The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K2O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ41K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K2O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ41K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K2O content and K isotope compositions (0.02–0.05 wt%; δ41K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation. 相似文献
毛乌素沙地处于中国季风区的西北边缘,对气候变化敏感,是古气候演化和古环境变迁研究的理想场所。全新世气温回暖期,气候整体稳定但存在暖湿冷干的次级波动,不同类型沉积相组成的地层序列记录了全新世千年、百年尺度的气候不稳定性。对毛乌素沙地不同沉积序列的研究表明:(1)毛乌素沙地东南缘的沙漠/黄土边界带DLT、NB剖面粒度及Rb/Sr比值可作为气候变化的代用指标。>63 μm砂含量增加,Rb/Sr比值降低,揭示东亚冬季风增强,风成砂堆积,风沙活动加剧,气候干冷;反之,东亚夏季风增强,降水增多,风化成壤程度加大,气候暖湿。(2)毛乌素沙地东南缘沙漠/黄土边界带及低洼沟谷区年代概率密度函数的分析显示,全新世早期~8\^5 ka BP风成砂堆积,风沙活动加剧,气候表现为干冷;全新世中期8\^5 ka~3\^0 ka BP地势较高处古土壤广泛发育,地势低洼处发育湖沼相/泥炭层,但在6.0 ka BP左右存在气候转冷过程;全新世晚期3\^0 ka BP以来气候波动频繁。(3)毛乌素沙地气候变化与北大西洋冰筏冷事件、董哥洞石笋、季风边缘区湖泊、东部沙地等记录具有可对比性和相对一致性,反映出全新世千年和百年尺度上的气候变化主要受全球变化的影响,这对预测和模拟未来气候变化具有借鉴意义。 相似文献
The factors affecting permeability change under repeated mining of coal seams are important study aspects that need to be explored. This study combined various stress variation characteristics of protective seam mining and simplified the stress path of repeated mining in protective seam mines. Based on the results from the bespoke gas flow and displacement testing apparatus, seepage tests for simulated repetitive mining were carried out. The results simulated the actual behavior very well. With any drastic increase in the mining influence, the axial deviation stress in the stress path increased, and the greater the difference in coal permeability during the unloading and stress recovery stage, the more substantial the increase in permeability. The change in coal permeability was significantly influenced by the severity of simulated repeated mining cycles. When the mining stress exceeded a critical value, the permeability of the coal sample increased with the increase in the number of loading and unloading cycles, but the reverse was true when the mining stress was lower than the critical value. The effective sensitivity of seepage to the applied stress decreased with an increase in the number of stress cycles. With a decrease in the deviation stress, that is, with lower severity of mining influence, the effective sensitivity of coal seepage to stress gradually decreased.
Natural Resources Research - In the past few decades, a variety of data-driven predictive modeling techniques has led to a dramatic advancement in mineral prospectivity mapping (MPM). The random... 相似文献
Common prestack fracture prediction methods cannot clearly distinguish multiplescale fractures. In this study, we propose a prediction method for macro- and mesoscale fractures based on fracture density distribution in reservoirs. First, we detect the macroscale fractures (larger than 1/4 wavelength) using the multidirectional coherence technique that is based on the curvelet transform and the mesoscale fractures (1/4–1/100 wavelength) using the seismic azimuthal anisotropy technique and prestack attenuation attributes, e.g., frequency attenuation gradient. Then, we combine the obtained fracture density distributions into a map and evaluate the variably scaled fractures. Application of the method to a seismic physical model of a fractured reservoir shows that the method overcomes the problem of discontinuous fracture density distribution generated by the prestack seismic azimuthal anisotropy method, distinguishes the fracture scales, and identifies the fractured zones accurately. 相似文献